Controlled free radical polymerization of methacrylates containG carbazole and cumarin pendant groups

Urszula Pisarek,

Mateusz Galica,

Dariusz Bogdał

Abstrakt

This paper presents the results of synthesis copolymers based on 2-(9-carbazolyl)ethyl methacrylate (CEM) and 7- (diethylamino)coumarin-3-carboxylic acid 2-(methacryloyloxy) ethyl ester (MK) using ATRP technique. The reactions were carried out both under conventional and microwave conditions. Various activations system with organic ligand 1,10-phenanthroline monohydrate were tested. Obtained polymers were characterized by GPC and UV-VIS techniques.

Słowa kluczowe: atom transfer radical polymerization, microwave irradiation, carbazole, coumarin, copolymer, luminescence