SIMPLIFIED METHODS FOR THE DETERMINATION OF HYDROGEN SULPHIDE ACID IN SEDIMENT CONTAMINATED BY MINING ACTIVITIES

Pekka Parvinen,

Krystyna Wieczorek-Ciurowa

Abstrakt

The concentration level of hydrogen sulphide acid in the sediment contaminated by mining activities can be applied as criteria ability of sediments to bind the heavy metals and mobility of such metals. The determination of hydrogen sulphide acid (HSA) by molecular absorption spectrometry and combustion-IR analysis in sediment samples is described. The liberation of H2S is performed through the addition of the concentrated sulphuric or hydrochloric acid. The liberated hydrogen sulphide is measured directly using molecular absorption spectrometry (MAS) and by absorbing the HSA in a silver nitrate solution and measuring the precipitated sulphur by combustion (the IR method). The lowest determinable concentrations were at the level of 2–10 mg g–1.

Słowa kluczowe: state of sediment, hydrogen sulphide acid determination, molecular absorption spectrometry, silver sulphide precipitation
References

Anwar J., Waheed-Uz-Zaman, Hameed A., Yasmeen F., J. Chem. Soc. Pak., 20/4, 1998, 235-239.

Müller B., Stierli R., Anal. Chim. Acta, 40, 1999, 257-264.

Cutter G.A., Oats T.J., Anal. Chem., 59, 1987, 717-721.

Lindsay W.L., Chemical Equilibria in Soil, John Wiley, New York 1979.

Crouzet C., Kedziorek M.A.M., Altmann R.S., Bourg A.C.M., Environ. Tech., 21, 2000, 285.

Di Toro D.M., Mahony J.D., Hansen D.J., Scott K.J., Hicks M.B., Mayr S.M., Remond M.S., Environ. Toxicol. Chem., 9, 1990, 1487-1502.

Leonard E.N., Mattson V.R., Benoit D.A., Hoke R.A., Ankley G.T., Hydrobiologia, 271, 1993, 87-95.

Fiedler H.D., Rubio R., Rauret G., Casals I., Talanta, 48, 1999, 403-407.

Crompton T.R., Determination of Anions, A Guide for the Analytical Chemist, Springer–Verlag, Berlin–Heidelberg 1996, 324-336.

Pawlak Z., Pawlak A.S., Talanta, 48, 1999, 347-353.

Tack F.M., Lapauw F., Verloo M.G., Talanta, 44, 1997, 2185-2192.

Brown K.A., McGreer E.R., Taekema B., Cullen J.T., Aquat. Geochem., 17, 2011, 821-839.

Syty A., Anal. Chem., 51, 1979, 911-914.

Parvinen P., Lajunen L.H.J., At Spectrosc., 15, 1994, 83-86.

Parvinen P., Wieczorek-Ciurowa K., Chem. Anal., 4, 1996, 477-481.

Parvinen P., Wieczorek-Ciurowa K., Chem. Anal., 50, 2005, 761-768.